Theory of crystallization in copolymers
Webb7 sep. 2016 · Polymer crystallization and melting are typically first-order phase transitions between the amorphous phase and the crystalline phase . When these two phases are in thermodynamic equilibrium, two phase transitions are thermodynamically reversible under a certain temperature. Webb29 dec. 2016 · The theory shows that entropic considerations, in addition to the traditional energetic arguments, can capture general trends of a vast range of phenomenology and …
Theory of crystallization in copolymers
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Webb12 apr. 2024 · This work aimed to study the thermal and crystalline properties of poly (1,4-phenylene sulfide)@carbon char nanocomposites. Coagulation-processed nanocomposites of polyphenylene sulfide were prepared using the synthesized mesoporous nanocarbon of coconut shells as reinforcement. The mesoporous reinforcement was synthesized using … Webb1 jan. 1991 · Crystallization in polymer blends is discussed in the framework of the recent advances in nucleation theories with the aim to highlight the most critical points for the prediction of the...
WebbThe thermodynamic data for macromonomers and polymers were calculated according to the theory of Flory and Vrij, which has been shown to describe well the melting behavior of linear PEO. It is shown that the melting parameters for macromonomers are identical to those of pure PEO in spite of the presence of the chain ends of different nature. The fraction of the ordered molecules in polymer is characterized by the degree of crystallinity, which typically ranges between 10% and 80%. Higher values are only achieved in materials having small molecules, which are usually brittle, or in samples stored for long time at temperatures just under the melting point. The latter procedure is costly and is applied only in special cases. Most methods of evaluating the degree of crystallinity assume a mixture of perfect crystalline an…
WebbThis article is published in Polymer.The article was published on 1981-09-01. It has received 21 citation(s) till now. Chrome Extension. Upload PDF Discover. Log in Sign up. Home. Tools. Citation generator. Chrome Extension. Home / Papers / Analysis of the crystallization kinetics of isotactic polypropylene by infra-red spectroscopy; Overview ... Webb458. BLOCK COPOLYMERS. Vol. 1. A standard notation for block copolymers is becoming accepted, whereby X-b-Y denotes a diblock copolymer of polymer X and polymer Y. However, sometimes the b is replaced by the full term block, or alternatively is omitted, and the diblock denoted X–Y.. A number of texts covering general aspects of block …
WebbPolymer crystallization under chain and space confinements is studied by Monte Carlo simulation. The simulation results show that the crystallinity and melting temperature of …
Webb22 nov. 2004 · A theory of oriented crystallization in elongated polymers having network structures (e.g., in vulcanized rubber) is developed through the application of statistical mechanical procedures similar to those employed in rubber elasticity theory. Expressions are derived which, within the limitation imposed by the simplifying assumptions, relate … how do wealth management companies make moneyWebb8 okt. 2024 · Polymer crystallization occurs in many plastic manufacturing processes, from injection molding to film blowing. Linear low-density polyethylene (LLDPE) is one of … how do wealth management firms make moneyWebb20 juli 2016 · Details of crystallization processes of a polymer at the crystallization temperature Tc from its melt kept initially at the melt temperature Tm depend profoundly … how do wealth managers get paidWebbAbstract Poly( l -lactide- co -e-caprolactone) [P(LLA-CL)] (82/18) film was made amorphous and a comparative study on the effects of rapid crystallization on the physical properties and mechanical properties of the film during hydrolytic degradation in phosphate-buffered solution and storage in the absence of water at 37 °C was carried out. ph of ketorolacWebb19 feb. 2024 · Alternatively, polymer crystallization kinetics may plausibly be manipulated by the overwhelming accepted theory of crystallization processes in polymer, known as Hoffman–Lauritzen theory. This theory takes into account thermally activated nucleation and diffusion phenomena occurring during polymer crystallization, which can be … how do wealth managers make moneyWebbA theory of necking in semi-crystalline polymers A. I. Leonov Department of Polymer Engineering, The University of Akron, Akron, Ohio 44325-0301, USA. Abstract Necking or cold drawing is a smoothed jump in cross-sectional area of long and thin bars (filaments or films) propagating with a constant speed. ph of kidneyWebb16 juli 2024 · ConspectusCrystallization of polymeric materials under nanoscopic confinement is highly relevant for nanotechnology applications. When a polymer is confined within rigid nanoporous anodic aluminum oxide (AAO) templates, the crystallization behavior experiences dramatic changes as the pore size is reduced, … ph of khp